Before being able to export (or import) mailboxes you will need to assign the 'Mailbox Import Export' role to the account you use for Exchange administration. This can be applied to an individual account or a security group. To assign the role you will need to run one of the following PowerShell...
Its easy to Export a Mailbox to PST using Mailbox Export Request in Exchange 2010Lets see on how to Export 1 single mailbox to PST in Exchange 2010To Acquire RBAC How to Export All the Mailboxes to PST. Step 1: Open Exchange Management Shell. Discovery Search (eDiscovery) (6).
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Lesson 1 representing relationships page 273 answers